Analytical chemistry council

METHODS AND OBJECTS OF CHEMICAL ANALYSIS

ISSN title: "Metody i obʺekty himičeskogo analiza"

An international journal devoted to all aspects of Analytical chemistry

ISSN 2413-6166 (Online), ISSN 1991-0290 (Print)

Kiev University
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Predicting the Composition of Qurna Crude Oil Fraction by Ternary Composition Diagram

Harith H. Al-Moameri*†, Ghanim Hassan‡, Mohammed Ali Abdulrehman†

* Corresponding authors
† Materials Engineering Department, University of Mustansiriyah, Baghdad, Iraq;

‡Middle Technical University, Baghdad, Iraq

*e-mail: almoamerih@uomustansiriyah.edu.iq

Methods Objects Chem. Anal., 2020, 15(1), p. 33-39

https://doi.org/10.17721/moca.2020.33-39  

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Abstract

With a goal to identify, and ultimately removing from the oil fraction, the carcinogenic components, an oil fraction oil has been analyzed into a main three hydrocarbon groups, paraffins, aromatics, and polycyclic saturates. A multi-stage adsorption apparatus has been used. Four units of 300 g alumina each seems to be sufficient for removing the polynuclear aromatics from 75 g of an oil fraction boiling between 365-375 °C from Qurna crude oil. The usefulness of the ternary diagram for analyzing the oil fraction to the three hydrocarbons groups has been studied and verified. An experimentally based linear relationship of density and refractive index was established to enable of identifying the composition of an oil fraction using the values on refractive index alone. Separation of uncontaminated paraffins requires higher adsorbent/ oil ratio and/or more significant number of adsorption units. Ensuring no overloading of the adsorbent was essential for the separation.

Keywords: adsorption, chemical analysis, prediction, separation, model

Article language: En


Publisher:Taras Shevchenko National University, Kiev Ukraine

(Analytical chemistry department at Taras Shevchenko National University, 64 Vladimirskaya STR., Kiev, 01601 UKRAINE)
analysis@univ.kiev.ua, www.univ.kiev.ua, +380-44-2393266

The journal is indexed in SCOPUS and Web of Science

The journal website: www.moca.net.ua

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